The recovery time increased from 21 to 89 s when the acetone concentration was increased from 50 to 750 ppm. Comparatively, the response time was shorter than the recovery time for the gas sensor in this study. The gas sensing mechanism for n-type semiconductor oxide sensors is surface-controlled and is controlled by the species and amount of oxygen ions on the surface [28]. The difference between the response time and recovery time revealed that the desorption reaction of oxygen molecules (release of electrons) was faster than the
adsorption process of oxygen molecules (trapping of electrons) on the surface of Batimastat solubility dmso the sample. A similar phenomenon was observed in a ZnO-based sensor tested in a reduced-gas environment [29]. Because the thickness of the ZGO crystallites ranges from 17 to 26 nm, the variation in resistance for the ZnO-ZGO sensor during gas sensing tests might be determined according to the resistance of the ZGO crystallites and contact regions between each cross-linked structure. Contact between oxides results in the formation of potential barriers [30, 31]. Recently, cross-linked 1D oxide nanostructures have indicated that potential barriers formed at the contact
regions play a crucial role in affecting gas sensing performance [32]. Efficient ethanol gas sensing for n-type 1D oxide nanostructures is attributed to electron donor-related oxygen vacancies in the nanostructures [33]. These factors Aspartate induced numerous depletion regions in ZnO-ZGO when exposed to ambient air in the current study; a clear resistance variation was further achieved in the sample upon exposure to the acetone gas. Figure 6 Time-dependent SBI-0206965 supplier current variation of the ZnO-ZGO heterostructures upon exposure to various acetone concentrations (50, 100, 250, 500, and 750 ppm) at 325°C. Conclusions We successfully prepared ZnO-ZGO heterostructures for UV light photoresponse and acetone gas sensing
applications by the sputter deposition of Ge ultrathin films onto ZnO nanowire templates after a high-temperature solid-state reaction. The ZGO crystallites were homogeneously formed on the surface of the residual ZnO underlayer, exhibiting a Ferrostatin-1 purchase rugged morphology. The XPS spectra and PL spectrum of the ZnO-ZGO heterostructures indicated the existence of surface crystal defects. The ZnO-ZGO heterostructures exhibited clear photocurrent sensitivity to UV light at room temperature and a gas sensing response to acetone in a concentration range of 50 to 750 ppm at 325°C. The detailed structural analyses in this study accounted for the observed UV light photoresponse and acetone gas sensing properties of the ZnO-ZGO heterostructures. Authors’ information YCL is a professor of the Institute of Materials Engineering at National Taiwan Ocean University (Taiwan). TYL is a graduate student of the Institute of Materials Engineering at National Taiwan Ocean University (Taiwan).