In more detail, after the Au deposition before annealing, the surface showed a quite smooth topography as clearly observed by the AFM

image in Figure 2a, and the line profile in Figure 2 (a-1) and the corresponding FFT spectrum in Figure 2 (a-2) showed a quite broad round pattern buy CH5424802 due to the narrow random surface modulation. At the T a of 250°C, the diffusion of Au adatoms was induced as shown in Figure 2b, but the surface modulation was only slightly increased as evidenced by the line profile in Figure 2 (b-1). The FFT spectrum in Figure 2 (b-2) became smaller with a round pattern. With the increased thermal energy at 300°C, the diffusion of adatoms was further enhanced, and as a result, there was nucleation of tiny Au clusters with a slightly bumpy morphology as shown in Figure 2c and (c-1). Finally, at the T a of 350°C, as clearly seen with the AFM image in Figure 2d and the line profile in Figure 2 (d-2), a sharp transition from

the https://www.selleckchem.com/products/E7080.html Au clusters to the wiggly nanostructures occurred with a height modulation of approximately ±10 nm as clearly evidenced by the line profiles of Figure 2 (c-1) and (d-1). The FFT pattern size was further reduced with the increased height modulation and became a symmetric circle as there was no apparent directionality of Au nanostructures. The Au clusters and wiggly nanostructures can be formed based on the Volmer-Weber growth mode [32, 33]. Given that the bonding energy among Au adatoms (E a) is greater than that between Au adatoms and GaAs surface atoms (E i), Au adatoms can be merged together to nucleate the Au clusters at a relatively lower T a, and the wiggly Au nanostructures

can result at an increased T a. This transition of surface morphology associated with the nucleation of the Au clusters and wiggly nanostructures appears to be unique to GaAs. For example, tuclazepam on Si (111) neither this type of transition nor the Au clusters or the wiggly Au nanostructures were observed during the evolution of the self-assembled Au droplets while varying the T a between 50°C and 850°C [34], but very high density dome-shaped Au droplets were observed throughout the temperature range. In short, with the increased T a on GaAs (111)A, apparent transitions of surface morphologies at each T a were clearly observed and the height modulation was gradually enlarged as a function of T a; a sharp transition was observed at 350°C with a surface modulation of approximately ±10 nm due to the increased diffusion of Au adatoms induced by the enhanced thermal energy. Figure 2 Nucleation of self-assembled Au clusters and wiggling nanostructures. The variation of annealing temperature (T a) done after 2.5-nm Au deposition on GaAs (111)A. The corresponding T a is indicated with labels in the (a-d) AFM top-view images of 1 × 1 μm2. (a-1) to (d-1) are the cross-sectional surface line profiles acquired from the white lines in (a) to (d). (a-2) to (d-2) show the corresponding 2-D FFT power spectra.